anhydrous ammonia: (MSDS) Material Safety Data Sheet

Tanner Industries, Inc. divisions: National Ammonia, Northeastern Ammonia, Hamler Industries, Bower Ammonia & Chemical
735 Davisville Road, Third Floor, Southampton, PA 18966; 215-322-1238

Corporate emergency telephone number: 800-643-6226
Chemtrec: 800-424-9300

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Description
Chemical Name: Ammonia, Anhydrous
CAS Registry No: 7664-41-7
Synonyms: Ammonia
Chemical Family: Inorganic Nitrogen Compound
Formula: NH₃
Molecular Weight: 17.03 (NH₃ )
Composition: 99+% Ammonia

Statement of Health Hazard
Hazard Description
Ammonia is an irritant and corrosive to the skin, eyes, respiratory tract and mucous membranes. Exposure to liquid or rapidly expanding gases may cause severe chemical burns and frostbite to the eyes, lungs and skin. Skin and respiratory related diseases could be aggravated by exposure.
• Not recognized by OSHA as a carcinogen
• Not listed in the National Toxicology Program
• Not listed as a carcinogen by the International Agency for Research on Cancer

Toxicity: LD 50, (Oral / Rat), 350 mg / kg

Physical Data
Boiling Point: -28°F at 1 atm
pH: N/A
Specific Gravity of Gas (air = 1): 0.596 at 32°F
Specific Gravity of Liquid (water = 1): 0.682 at -28°F (compared to water at 39°F)
Percent Volatile: 100% at 212°F
Appearance and Odor: Colorless liquid or gas with pungent odor
Critical Temperature: 271.4°F
Gas Specific Volume: 20.78 Ft³/lb at 32°F and 1 atm
Vapor Density (air = 1): 0.0481 Lb/Ft³ at 32°F
Liquid Density: 38.00 Lb/Ft³ at 70° F
Approximate Freezing Point: -108°F
Weight (per gallon): 5.15 pounds at 60°F
Vapor Pressure: 114 psig 70°F
Solubility in Water (per 100 pounds of water): 86.9 pounds at 32°F,
51 pounds at 68°F
Surface Tension: 23.4 Dynes / cm at 52°F
Critical Pressure: 111.5 atm

Emergency Treatment
Effects of Overexposure
Eye: Tearing, edema or blindness may occur.
Skin: Irritation, corrosive burns, blister formation may result. Contact with liquid may produce a caustic burn and frostbite.
Inhalation: Acute exposure may result in severe irritation of the respiratory tract, bronchospasm, pulmonary edema or respiratory arrest.
Ingestion: Lung irritation and pulmonary edema may occur. Extreme exposure may result in death from spasm, inflammation or edema. Brief inhalation exposure to 5,000 ppm may be fatal.
 
Emergency Aid: Remove patient to uncontaminated area
Eye: Flush with copious amounts of tepid water for a minimum of 20 minutes. Eyelids should be held apart and away from eyeball for thorough rinsing.
Skin: Flush with copious amounts of tepid water for a minimum of 20 minutes while removing contaminated clothing, jewelry and shoes. Do not rub or apply ointment on affected area. Clothing may initially freeze to skin. Thaw frozen clothing from skin before removing.
Inhalation: Remove to fresh air. If not breathing, administer artificial respiration. If trained to do so, administer supplemental oxygen, if required.
Ingestion: If conscious, give large amounts of water to drink. May drink orange juice, citrus juice or diluted vinegar (1:4) to counteract ammonia. If unconscious, do not give anything by mouth. DO NOT INDUCE VOMITING!

SEEK IMMEDIATE MEDICAL HELP FOR ALL EXPOSURES!

Note to Physician
Respiratory injury may appear as a delayed phenomenon. Pulmonary edema may follow chemical bronchitis. Supportive treatment with necessary ventilation actions, including oxygen, may warrant consideration.

Fire and Explosion Hazard Data
Flashpoint: None
Flammable Limits in Air: LEL/UEL 16% to 25% (listed in the NIOSH Pocket Guide to Chemical Hazards 15% to 28%)
Extinguishing Media: Dry Chemical, CO₂, water spray or alcohol-resistant foam if gas flow cannot be stopped
Auto Ignition Temperature: 1,204°F (If catalyzed), 1,570°F (If un-catalyzed)

Special Fire-Fighting Procedure
Must wear protective clothing and a positive pressure SCBA. Stop source if possible. If a portable container (such as a cylinder or trailer) can be moved from the fire area without risk to the individual, do so to prevent the pressure relief valve of the trailer from discharging or the cylinder from rupturing. Fight fires using dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Cool fire exposed containers with water spray. Stay upwind when containers are threatened. Use water spray to knock down vapor and dilute.
 
Unusual Fire and Explosion Hazards
• Outdoors, ammonia is not generally a fire hazard. Indoors, in confined areas, ammonia may be a fire hazard, especially if oil and other combustible materials are present. Combustion may form toxic nitrogen oxides.
• If relief valves are inoperative, heat exposed storage containers may become explosion hazards due to over pressurization.

Chemical Reactivity
Stability
Stable at room temperature. Heating a closed container above room temperature causes vapor pressure to increase rapidly. Anhydrous ammonia will react exothermically with acids and water. Will not polymerize.
 
Conditions to Avoid
Anhydrous ammonia has potentially explosive reactions with strong oxidizers. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, ethanol, fluorine and silver nitrate. Anhydrous ammonia reacts to form explosive products, mixtures or compounds with mercury, gold, silver, iodine, bromine and silver oxide. Avoid anhydrous ammonia contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. Avoid anhydrous ammonia contact with galvanized surfaces, copper, brass, bronze, aluminum alloys, mercury, gold and silver. A corrosive reaction will occur.
 
Hazardous Decomposition Products
Anhydrous ammonia decomposes to hydrogen and nitrogen gases above 450°C (842°F). Decomposition temperatures may be lowered by contact with certain metals, such as iron, nickel and zinc and by catalytic surfaces such as porcelain and pumice.

Spill or Leak Procedures
Steps to be Taken
Stop source of leak if possible, provided it can be done in a safe manner. Leave the area of a spill by moving laterally and upwind. Isolate the affected area. Non-responders should evacuate the area, or shelter in place. Only properly trained and equipped persons should respond to an ammonia release. Wear eye, hand and respiratory protection and protective clothing; see PROTECTIVE EQUIPMENT. Stay upwind and use water spray downwind of container to absorb the evolved gas. Contain spill and runoff from entering drains, sewers, and water systems by utilizing methods such as diking, containment, and absorption. CAUTION: ADDING WATER DIRECTLY TO LIQUID SPILLS WILL INCREASE VOLATILIZATION OF AMMONIA, THUS INCREASING THE POSSIBILITY OF EXPOSURE.

Waste Disposal
Listed as hazardous substance under CWA (40 CFR 116.4, 40 CFR 117.3). Reportable Quantity 100 pounds. Classified as hazardous waste under RCRA (40CFR 261.22 Corrosive #D002). Comply with all regulations. Suitably diluted product may be disposed of on agricultural land as fertilizer. Keep spill from entering streams, lakes, or any water systems.

Special Protection and Procedures
Respiratory Protection
Respiratory protection approved by NIOSH/MSHA for ammonia must be used when applicable safety and health exposure limits are exceeded. For escape in emergencies, MSHA/NIOSH approved respiratory protection that consists of a full-face gas mask and canisters approved for ammonia is required. Refer to 29 CFR 1910.134 and ANSI: Z88.2 for requirements and selection. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH).

Eye Protection
Chemical splash goggles should be worn when handling anhydrous ammonia. A face shield can be worn over chemical splash goggles as additional protection. Do not wear contact lenses when handling anhydrous ammonia.
 
Ventilation
Local exhaust should be sufficient to keep ammonia vapor to 25 ppm or less.

Protective Equipment
• At a minimum, splash proof, chemical safety goggles, ammonia resistant, gloves (such as rubber), and ammonia-impervious clothing should be worn to prevent contact during normal loading, unloading and transfer operations and handling small spills. Face shield and boots can be worn as additional protection.
• Respiratory protection approved by NIOSH/MSHA for ammonia must be used when applicable safety and health exposure limits are exceeded. For a hazardous material release response, Level A and/or Level B ensemble including positive-pressure SCBA should be used. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). Refer to 29 CFR 1910.132 through 1910.138 for personal protective equipment requirements.

Special Precautions
Storage and Handling
Only trained persons should handle anhydrous ammonia. Store in cool (26.7°C / 80°F) and well-ventilated areas, with containers tightly closed. OSHA 29 CFR 1910.111 prescribes handling and storage requirements for anhydrous ammonia as a hazardous material. Use only stainless steel, carbon steel or black iron for anhydrous ammonia containers or piping. Do not use plastic. Do not use any non-ferrous metals such as copper, brass, bronze, aluminum, tin, zinc or galvanized metals. Protect containers from physical damage. Keep away from ignition sources, especially in indoor spaces.
 
Work-Place Protective Equipment
Protective equipment should be stored near, but outside of anhydrous ammonia area. Water for first aid, such as an eyewash station and safety shower, should be kept available in the immediate vicinity. See 29 CFR 1910.111 for workplace requirements.
 
Disposal
See WASTE DISPOSAL. Classified as RCRA Hazardous Waste due to corrosivity with designation D002, if disposed of in original form.

Labeling and Shipping
Hazard Class: (US Domestic): 2.2 (Non-Flammable Gas) (International): 2.3 (Poison Gas) subsidiary 8 (Corrosive)
Proper Shipping Description:
• (US Domestic): Ammonia, Anhydrous, 2.2, UN1005, RQ, Inhalation Hazard
• (International): Ammonia, Anhydrous, 2.3, (8), UN1005, RQ, Poison-Inhalation Hazard Zone “D”
Placard: (US Domestic): Non-Flammable Gas,
(International): Poison Gas, Corrosive (Subsidiary)
Identification No: UN 1005
National Fire Protection Assoc. Hazardous Rating and Hazardous Materials Identification System Labels:
            Anhydrous Ammonia
            HEALTH = 3
            FLAMMABILITY = 1
            REACTIVITY = 0
            PERSONAL PROTECTION = H

Other Regulatory Requirements
Under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA), Section 103, any environmental release of this chemical equal to or over the reportable quantity of 100 lbs. must be reported promptly to the National Response Center, Washington, D.C. (1-800-424-8802).

The material is subject to the reporting requirements of Section 304, Section 312 and Section 313, Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR 372. Emergency Planning & Community Right to Know Act, (EPCRA) extremely hazardous substance, 40 CFR 355, Title III, Section 302 – Ammonia, Threshold Planning Quantity (TPQ) 500 lbs.

EPA Hazard Categories – Immediate: Yes; Delayed: No; Fire: No; Sudden Release: Yes; Reactive: No.

Clean Air Act – Section 112(r): Material is listed under EPA’s Risk Management Program (RMP), 40 CFR Part 68, at storage/process amounts greater than the Threshold Quantity (TQ) of 10,000 lbs.

Disclaimer
The information, data, and recommendations in this material safety data sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. The information, data, and recommendations set forth herein are believed by us to be accurate. We make no warranties, either expressed or implied, with respect thereto and assume no liability in connection with any use of such information, data, and recommendations.

Revision: September 2005                    Prepared By: JRP

Tanner Industries, Inc. 1-800-643-6226